Inorganic Chemistry Acs: Study Guide Verified Questions And Answers

discuss the pH dependence of redox reactions {Ans: as pH increases, E decreases. As pH decreases, E increases, this is due to the fact that any redox reactions require H+ ions, and a greater abundance of them increase the amount of current that can be transferred}what characteristics of the complex makes a MLCT likely to occur {Ans: if a complex has ligands with low lying pi star orbitals, especially with aromatics, a MLCT is likely to occur}band theory s band {Ans: forms between s orbitals}what is spin orbital coupling {Ans: the relative orientation of spin and angular momenta of each electron}how are the term energies expressed on the axes {Ans: E/B on y plotted against delta/B on x. B is rajah parameter}Plyatomic MO {Ans: must use approximations of MO theory. Linear combinations of Atomic orbitals create a cumulative approximation of the atomic orbitals of its constituent atoms, compare orbitals to determine what will mix}